Evidence map›Paper›PMID 39349448›Full record

ArticleNature communications2024

Potential cycling boosts the electrochemical conversion of polyethylene terephthalate-derived alcohol into valuable chemicals.

Gui Zhao, Jiayi Lin, Mengying Lu, Lina Li, Pengtao Xu, Xi Liu, Liwei Chen

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Direct Electrosynthesis of Glycolate From Carbon Dioxide.Angewandte Chemie (International ed. in English) · 2026
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Gui ZhaoSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China.ORCID http://orcid.org/0000-0002-3623-2060
Jiayi LinSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China.
Mengying LuSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China.
Lina LiShanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Shanghai, PR China.
Pengtao XuSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China. xupengtao@sjtu.edu.cn.ORCID http://orcid.org/0000-0002-4470-446X
Xi LiuSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China. liuxi@sjtu.edu.cn.ORCID http://orcid.org/0000-0002-8654-0774
Liwei ChenSchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai, PR China. lwchen2018@sjtu.edu.cn.ORCID http://orcid.org/0000-0003-4160-9771

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22072090, 22272106, 21991153, 21991150, 22372099
6 · The paper itself

Abstract

The electrocatalytic valorization of polyethylene terephthalate-derived ethylene glycol to valuable glycolic acid offers considerable economic and environmental benefits. However, conventional methods face scalability issues due to rapid activity decay of noble metal electrocatalysts. We demonstrate that a dynamic potential cycling approach, which alternates the electrode potential between oxidizing and reducing values, significantly mitigates surface deactivation of noble metals during electrochemical oxidation of ethylene glycol. This method enhances catalyst activity by 20 times compared to a constant-potential approach, maintaining this performance for up to 60 h with minimal deactivation. In situ Raman and X-ray absorption spectroscopy show that this effectiveness results from efficient removal of surface oxide during the reaction. The strategy is applicable to polyethylene terephthalate hydrolysates and various noble metals, such as palladium, gold, and platinum, with palladium showing a high conversion rate in recent studies. Our approach offers an efficient and durable method for electrochemical upcycling of biomass-derived compounds.

Identifiers

PMID39349448
PMCPMC11442646

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.