Evidence map›Paper›PMID 39348510›Full record

ArticleJournal of the American Chemical Society2024

β-Selective 2-Deoxy- and 2,6-Dideoxyglucosylations Catalyzed by Bis-Thioureas.

Peyton D Beyer, Michael M Nielsen, Elias Picazo, Eric N Jacobsen

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Article
  3. Confined Acids Catalyze a Broadly Applicable β-SelectiveJournal of the American Chemical Society · 2026
    Article
  4. Article
  5. Mechanism of 3-The Journal of organic chemistry · 2025
    Article
  6. Article
  7. Review
  8. Article
  9. Article
  10. Stereoselective Approaches to β-Linked 2-Deoxy Sugars.Molecules (Basel, Switzerland) · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Peyton D BeyerDepartment of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.ORCID 0000-0001-7002-6730
Michael M NielsenDepartment of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.
Elias PicazoDepartment of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.ORCID 0000-0001-5153-4131
Eric N JacobsenDepartment of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.ORCID 0000-0001-7952-3661

Funding

Development, Elucidation, and Application of New Principles in Stereoselective CatalysisR35GM149244 · NIGMS · HARVARD UNIVERSITY · PI ERIC N JACOBSEN · 2023 to 2026
$3.2M
Broadly Applicable, Small Molecule Catalysts for Stereoselective and Site-Selective Glycosylation ReactionsR01GM132571 · NIGMS · HARVARD UNIVERSITY · PI JACOBSEN, ERIC N · 2019 to 2022
$1.4M
Synthesis and Characterization of Nitrogen and Sulfur Donor-Acceptor Stenhouse AdductsR00GM140070 · NIGMS · UNIVERSITY OF SOUTHERN CALIFORNIA · PI PICAZO, ELIAS · 2022 to 2024
$932k
Strategic Molecular Activations for the Selective Synthesis of 2-Deoxy-Beta-Glycosides, and for the Synthesis of Novel Donor-Acceptor Stenhouse AdductsK99GM140070 · NIGMS · HARVARD UNIVERSITY · PI PICAZO, ELIAS · 2021 to 2021
$100k
NIGMS NIH HHS K99 GM140070NIGMS NIH HHS R00 GM140070NIGMS NIH HHS R01 GM132571NIGMS NIH HHS R35 GM149244
6 · The paper itself

Abstract

We present methods for β-selective 2-deoxy- and 2,6-dideoxyglucosylations of natural products, carbohydrates, and amino acids using bis-thiourea hydrogen-bond-donor catalysts. Disarming ester protecting groups were necessary to counter the high reactivity of 2-deoxyglycosyl electrophiles toward non-stereospecific S

Identifiers

PMID39348510
PMCPMC11905915

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.