ArticleJournal of the American Chemical Society2024
Isolation of the Secondary Building Unit of a 3D Metal-Organic Framework through Clip-Off Chemistry, and Its Reuse To Synthesize New Frameworks by Dynamic Covalent Chemistry.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Excision in Reduced Dimensionality: Synthesis of 1D Covalent Organic Framework via Clip-off Chemistry.Angewandte Chemie (International ed. in English) · 2026Article
- Porous Organic Cages as Building Blocks for Framework Materials.Angewandte Chemie (International ed. in English) · 2025Review
- Converging the Complementary Traits of Metal-Organic Frameworks and Covalent Organic Frameworks.ACS applied materials & interfaces · 2025Review
- Concentration Gradient-Induced Syntheses and Crystal Structures of Two Copper(II) Coordination Polymer Based on Phthalic Acid and 2,2'-Bipyridine.Molecules (Basel, Switzerland) · 2025Article
- Merging and Clipping Nets for the Synthesis of Three- and Two-Merged Net Metal-Organic Frameworks.Journal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Herein, we present a novel methodology for synthesizing metal clusters or secondary building units (SBUs) that are subsequently employed to construct innovative metal-organic frameworks (MOFs) via dynamic covalent chemistry. Our approach entails extraction of SBUs from preformed MOFs through complete disassembly by clip-off chemistry. The initial MOF precursor is designed to incorporate the desired SBU, connected exclusively by cleavable linkers (in this study, with olefinic bonds). Cleavage of all the organic linkers (in this study, via ozonolysis under reductive conditions) liberates the SBUs functionalized with aldehyde groups. Once synthesized, these SBUs can be further reacted with amines in dynamic covalent chemistry to build new, rationally designed MOFs.
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Registered trials
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