Evidence map›Paper›PMID 39339349›Full record

ReviewMolecules (Basel, Switzerland)2024

Catalytic Reduction of Aromatic Nitro Compounds to Phenylhydroxylamine and Its Derivatives.

Min Yu, Dachen Ouyang, Liqiang Wang, You-Nian Liu

Abstract readReview
In one paragraph

Review in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Review
  2. Article
  3. Review
  4. Article
  5. Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Min YuHunan Provincial Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
Dachen OuyangHunan Provincial Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
Liqiang WangHenan Province Industrial Technology Research Institute of Resources and Materials, School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.ORCID 0000-0002-4579-7258
You-Nian LiuHunan Provincial Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.ORCID 0000-0002-7078-5937

Funding

Hunan Provincial Science and Technology Plan Project, China No.2019TP1001Key Scientific Research Project of Colleges 21A530005National Natural Science Foundation of China No. 22008221National Natural Science Foundation of China No. 22238013
6 · The paper itself

Abstract

Phenylhydroxylamine and its derivates (PHAs) are important chemical intermediates. Phenylhydroxylamines are mainly produced via the catalytic reduction of aromatic nitro compounds. However, this catalytic reduction method prefers to generate thermodynamically stable aromatic amine. Thus, designing suitable catalytic systems, especially catalysts to selectively convert aromatic nitro compounds to PHAs, has received increasing attention but remains challenging. In this review, we initially provide a brief overview of the various strategies employed for the synthesis of PHAs, focusing on reducing aromatic nitro compounds. Subsequently, an in-depth analysis is presented on the catalytic reduction process, encompassing discussions on catalysts, reductants, hydrogen sources, and a comprehensive assessment of the merits and drawbacks of various catalytic systems. Furthermore, a concise overview is provided regarding the progress made in comprehending the mechanisms involved in this process of catalytic reduction of aromatic nitro compounds. Finally, the main challenges and prospects in PHAs' production via catalytic reduction are outlined.

Indexed as

aromatic nitro compoundscatalytic reductionphenylhydroxylaminereduction mechanism

Identifiers

PMID39339349
PMCPMC11433948

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.