Photo-Crosslinked Polyurethane-Containing Gel Polymer Electrolytes via Free-Radical Polymerization Method.

Fatmanur Uyumaz, Yerkezhan Yerkinbekova, Sandugash Kalybekkyzy, Memet Vezir Kahraman

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Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 authors.

Fatmanur UyumazDepartment of Chemistry, Faculty of Science, Marmara University, Istanbul 34722, Turkey.

Yerkezhan YerkinbekovaNational Laboratory Astana, Nazarbayev University, Astana 010000, Kazakhstan.ORCID 0000-0002-1781-345X

Sandugash KalybekkyzyNational Laboratory Astana, Nazarbayev University, Astana 010000, Kazakhstan.ORCID 0000-0002-7586-719X

Memet Vezir KahramanDepartment of Chemistry, Faculty of Science, Marmara University, Istanbul 34722, Turkey.ORCID 0000-0003-1043-6476

Funding

Marmara University Scientific Research Commission Project #FYL-2022-10510Ministry of Science and Higher Education of the Republic of Kazakhstan #AP14871520

6 · The paper itself

Abstract

Using a novel technique, crosslinked gel polymer electrolytes (GPEs) designed for lithium-ion battery applications have been created. To form the photo crosslink via free-radical polymerization, a mixture of polyurethane acrylate (PUA), polyurethane methacrylate (PUMA), vinyl phosphonic acid (VPA), and bis[2-(methacryloyloxy)ethyl] phosphate (BMEP) was exposed to ultraviolet (UV) radiation during the fabrication process. The unique crosslinked configuration of the membrane increased its stability and made it suitable for use with liquid electrolytes. The resulting GPE has a much higher ionic conductivity (1.83 × 10

Indexed as

free-radical polymerizationgel polymer electrolytelithium-ion batterypolyurethane acrylatepolyurethane methacrylateUV-crosslinking

Identifiers

PMID39339092

DOI10.3390/polym16182628

PMCPMC11435539

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