Evidence map›Paper›PMID 39339042›Full record

ArticlePolymers2024

Benzodiazole-Based Covalent Organic Frameworks for Enhanced Photocatalytic Dehalogenation of Phenacyl Bromide Derivatives.

Ming Wang, Jiaying Qian, Shenglin Wang, Zhongliang Wen, Songtao Xiao, Hui Hu, Yanan Gao

Abstract read
In one paragraph

Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Ming WangKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.
Jiaying QianKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.
Shenglin WangKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.
Zhongliang WenKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.
Songtao XiaoChina Institute of Atomic Energy, Beijing 102413, China.
Hui HuKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.
Yanan GaoKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No. 58, Renmin Avenue, Haikou 570228, China.ORCID 0000-0002-5543-6296

Funding

Key Research and Development Project of Hainan Province, China ZDYF2024GXJS005National Natural Science Foundation of China 21965011the Major Science and Technology Plan of Hainan Province, China ZDKJ202016
6 · The paper itself

Abstract

Covalent organic frameworks (COFs) have garnered significant interest within the scientific community due to their distinctive ability to act as organic semiconductors responsive to visible light. This unique attribute makes them up-and-coming candidates for facilitating photocatalytic organic reactions. Herein, two donor-acceptor COFs, TPE-BSD-COF and TPE-BD-COF, have been designed and synthesized by incorporating electron-rich tetraphenylethylene and electron-deficient benzoselenadiazole and benzothiadiazole units into the framework through a Schiff-base polycondensation reaction. Both COFs exhibit exceptional crystallinity and enduring porosity. TPE-BSD-COF and TPE-BD-COF exhibit broad light absorption capabilities, a narrow optical band gap, and low electrochemical impedance spectrum (EIS) levels, indicating that the two COFs are effective heterogeneous photocatalysts for the reductive dehalogenation of phenacyl bromide derivatives under blue LED irradiation. A high photocatalytic yield of 98% and 95% was achieved by TPE-BSD-COF and TPE-BD-COF catalysts, respectively, within only one hour.

Indexed as

covalent organic frameworksdehalogenationheterogeneous photocatalysisheteropore

Identifiers

PMID39339042
PMCPMC11435578

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.