ArticleAngewandte Chemie (International ed. in English)2025
Switching Sides: Regiochemistry and Functionalization Dictate the Photoswitching Properties of Imines.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Mechanically Interlocked Indigo Photoswitches.Angewandte Chemie (International ed. in English) · 2026Article
- Photorheological action plots.Chemical science · 2026Article
- Turn-on fluorescence switching and radical formation in a dual-functional negative photochromic dimethyldihydropyrene.Chemical science · 2026Article
- Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications.Chemical record (New York, N.Y.) · 2026Article
- White-light powered autonomous molecular ratchet drives PdChemical science · 2026Article
- Heteroaryl iminothioindoxyl (HA-ITI) photoswitchesChemical science · 2026Article
- Light them up: photoresponsive imine-containing systems.Chemical science · 2025Review
- All-photonic switching of a benzo[Chemical science · 2025Article
- Introducing Photochemical Action Plots as a Tool for Unlocking On-Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst.Angewandte Chemie (International ed. in English) · 2025Article
- Enhancing the Photoswitching Properties ofJournal of the American Chemical Society · 2025Article
- Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch.Angewandte Chemie (International ed. in English) · 2025Article
- Switching Sides: Regiochemistry and Functionalization Dictate the Photoswitching Properties of Imines.Angewandte Chemie (International ed. in English) · 2025Article
- Photoswitches beyond azobenzene: a beginner's guide.Beilstein journal of organic chemistry · 2025Review
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Authors and funding
3 authors.
Funding
Abstract
Photoswitchable imines demonstrate light-dependent dynamic covalent chemistry and can function as molecular ratchets. However, the design of aryliminopyrazoles (AIPs) has been limited to N-pyrazole derivatives with ortho-pyrrolidine motifs. The impact of other functionalization patterns on the photoswitching properties remains unknown. Here, we present a systematic structure-property analysis and study how the photoswitching properties can be tuned through ortho- and para-functionalization of the phenyl ring in N-pyrazole and N-phenyl AIPs. This study establishes the first set of design rules for these AIP photoswitches and reports the most stable Z-isomer of an AIP to date, enabling its crystallization and resulting in the first reported crystal structure of a metastable Z-aldimine. Finally, we demonstrate that the AIPs are promising candidates for photoswitching in the condensed phase.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.