Evidence map›Paper›PMID 39322620›Full record

ArticleAngewandte Chemie (International ed. in English)2025

Stereocontrolled Synthesis of Chiral Helicene-Indenido ansa- and Half-Sandwich Metal Complexes and Their Use in Catalysis.

Tereza Edlová, Jiří Rybáček, Hélène Cattey, Jaroslav Vacek, Lucie Bednárová, Pierre Le Gendre, Adrien T Normand, Irena G Stará, Ivo Starý

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Tereza EdlováInstitut de Chimie Moléculaire de, L'Université de Bourgogne (ICMUB), 9 avenue Alain Savary, Dijon, 21000, France.ORCID https://orcid.org/0000-0003-2100-7431
Jiří RybáčekInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 542/2, 160 00, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0003-2846-5451
Hélène CatteyInstitut de Chimie Moléculaire de, L'Université de Bourgogne (ICMUB), 9 avenue Alain Savary, Dijon, 21000, France.ORCID https://orcid.org/0000-0002-4416-7510
Jaroslav VacekInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 542/2, 160 00, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-2610-4444
Lucie BednárováInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 542/2, 160 00, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0003-3367-0193
Pierre Le GendreInstitut de Chimie Moléculaire de, L'Université de Bourgogne (ICMUB), 9 avenue Alain Savary, Dijon, 21000, France.
Adrien T NormandInstitut de Chimie Moléculaire de, L'Université de Bourgogne (ICMUB), 9 avenue Alain Savary, Dijon, 21000, France.ORCID https://orcid.org/0000-0002-8047-9386
Irena G StaráInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 542/2, 160 00, Prague 6, Czech Republic.ORCID https://orcid.org/0000-0002-5267-9604
Ivo StarýInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 542/2, 160 00, Prague 6, Czech Republic.

Funding

Grantová Agentura České Republiky 22-18773SÚstav organické chemie a biochemie Akademie věd České republiky 61388963
6 · The paper itself

Abstract

Despite recent tremendous progress in the synthesis of nonplanar chiral aromatics, and helicenes in particular, their conversion to half-sandwich or sandwich transition metal complexes still lags behind, although they represent an attractive family of modular and underexplored chiral architectures with a potential catalytic use. In this work, starting from various chiral helicene-indene proligands, we prepared the enantio- and diastereopure oxa[6]- and oxa[7]helicene-indenido half-sandwich Rh

Indexed as

ansa-metalloceneC−H activationenantioselective catalysishalf-sandwich complexeshelicenes

Identifiers

PMID39322620
PMCPMC11701364

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.