Evidence map›Paper›PMID 39318071›Full record

ArticleChemistryOpen2024

Impact of Ligand Design on an Iron NHC Epoxidation Catalyst.

Tim P Schlachta, Greta G Zámbó, Michael J Sauer, Isabelle Rüter, Fritz E Kühn

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemistryOpen, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Formation of a diiron-(μ-ηActa crystallographica. Section C, Structural chemistry · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Tim P SchlachtaTechnical University of Munich, School of Natural Sciences, Department of Chemistry and Catalysis Research Center, Molecular Catalysis, Lichtenbergstraße 4, 85748, Garching, Germany.ORCID https://orcid.org/0000-0002-6343-2818
Greta G ZámbóTechnical University of Munich, School of Natural Sciences, Department of Chemistry and Catalysis Research Center, Molecular Catalysis, Lichtenbergstraße 4, 85748, Garching, Germany.ORCID https://orcid.org/0000-0002-1515-557X
Michael J SauerTechnical University of Munich, School of Natural Sciences, Department of Chemistry and Catalysis Research Center, Molecular Catalysis, Lichtenbergstraße 4, 85748, Garching, Germany.
Isabelle RüterInstitut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, 37077, Göttingen, Germany.ORCID https://orcid.org/0000-0003-0901-8162
Fritz E KühnTechnical University of Munich, School of Natural Sciences, Department of Chemistry and Catalysis Research Center, Molecular Catalysis, Lichtenbergstraße 4, 85748, Garching, Germany.ORCID https://orcid.org/0000-0002-4156-780X

Funding

Deutsche Forschungsgemeinschaft (DFG) 445916766
6 · The paper itself

Abstract

An open-chain iron pyridine-NHC framework is expanded utilizing a benzimidazole moiety to deepen the understanding of the impact of electronic variations on iron NHC epoxidation catalysts, especially regarding the stability. The thereby newly obtained iron(II) NHC complex is characterized and employed in olefin epoxidation. It is remarkably temperature tolerant and achieves a TOF of ca. 10 000 h

Indexed as

Carbene ligandsEpoxidationIron NHC complexesNon-heme iron complexesTailoring catalytic properties

Identifiers

PMID39318071
PMCPMC11625922

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.