ArticleThe journal of physical chemistry. B2024
Molecular-Scale Interactions in the Choline Chloride-Ethylene Glycol Deep Eutectic Solvent System: The Importance of Chromophore Charge in Mediating Rotational Dynamics.
Article in The journal of physical chemistry. B, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The trial behind it
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Who cites it
4 citing papers in PubMed.
- Insights into Rotational and Translational Dynamics in Mixtures of Ethylene Glycol and Choline Chloride Using Nuclear Magnetic Resonance Techniques.The journal of physical chemistry. B · 2026Article
- The Direct Piezoelectric Effect in Deep Eutectic Solvents.Journal of the American Chemical Society · 2026Article
- Do Dipolar Cosolvents Mitigate Microheterogeneity in Deep Eutectic Solvents? Solvation Dynamics and Solute Rotations in Glyceline/Methanol Solutions.The journal of physical chemistry. B · 2026Article
- The Importance of Hydrogen Bonded Networks in the Dynamic Heterogeneity of Deep Eutectic Solvents.The journal of physical chemistry. B · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report on the rotational diffusion dynamics of three chromophores (disodium fluorescein, oxazine 725, and perylene) in a series of choline chloride-ethylene glycol (ChCl:EG) deep eutectic solvent (DES) systems. We observe behavior independent of DES bulk viscosity for the cationic and neutral probes and behavior that is consistent with stick-limit interactions for the modified Debye-Stokes-Einstein model for the anionic probe. This finding indicates that the anionic species is integral to the interactions between DES constituent species that are responsible for local organization, consistent with previous MD simulations that showed higher interaction energies associated with both the hydrogen bond donor (EG) and hydrogen bond acceptor (Ch
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Registered trials
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