Evidence map›Paper›PMID 39316295›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Unveiling the Dynamic Pathways of Metal-Organic Framework Crystallization and Nanoparticle Incorporation for Li-S Batteries.

Xiaohui Song, Rui Huang, Xingyu Zhang, Qiang Chang, Semi Kim, Daeun Jeong, Qian Hou, Juyeong Kim, Edison Huixiang Ang, Xiaowei Su and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Xiaohui SongSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.ORCID https://orcid.org/0000-0003-2523-2556
Rui HuangSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.
Xingyu ZhangSchool of Mathematics, Statistics and Mechanics, Beijing University of Technology, Beijing, 100124, P. R. China.
Qiang ChangSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.
Semi KimDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju, 52828, South Korea.
Daeun JeongDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju, 52828, South Korea.
Qian HouSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.
Juyeong KimDepartment of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju, 52828, South Korea.
Edison Huixiang AngNatural Sciences and Science Education, National Institute of Education, Nanyang Technological University, Singapore, 637616, Singapore.
Xiaowei SuAnhui Honghai New Materials Co., Ltd, Anqing, Anhui, 246100, P. R. China.
Xuyong FengSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.
Hongfa XiangSchool of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.

Funding

Basic Science Research Program 2022R1A4A1022252Dongguan City Survey Project on the Generation, Collection, and Utilization of Scrap Power Batteries W2023JSFW0787Fundamental Research Funds for the Central Universities PA2024GDGP0042KBSI NFEC 2019R1A6C1010042Major Science and Technology Projects in Anhui Province 2022e03020004Start-up Grant from Hefei University of Technology 13020-03712021026Start-up Grant from Hefei University of Technology PA2024GDGP0042
6 · The paper itself

Abstract

Metal-organic frameworks (MOFs) present diverse building blocks for high-performance materials across industries, yet their crystallization mechanisms remain incompletely understood due to gaps in nucleation and growth knowledge. In this study, MOF structural evolution is probed using in situ liquid phase transmission electron microscopy (TEM) and cryo-TEM, unveiling a blend of classical and nonclassical pathways involving liquid-liquid phase separation, particle attachment-coalescence, and surface layer deposition. Additionally, ultrafast high-temperature sintering (UHS) is employed to dope ultrasmall Cobalt nanoparticles (Co NPs) uniformly within nitrogen-doped hard carbon nanocages confirmed by 3D electron tomography. Lithium-sulfur battery tests demonstrate the nanocage-Co NP structure's exceptional capacity and cycling stability, attributed to Co NP catalytic effects due to its small size, uniform dispersion, and nanocage confinement. The findings propose a holistic framework for MOF crystallization understanding and Co NP tunability through ultrafast sintering, promising advancements in materials science and informing future MOF synthesis strategies and applications.

Indexed as

3D tomographyin situ liquid phase TEMlithium–sulfur batteryMOFultrafast high‐temperature sinter

Identifiers

PMID39316295
PMCPMC11578323

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.