Evidence map›Paper›PMID 39315673›Full record

ArticleAngewandte Chemie (International ed. in English)2024

An Expedient Route to Bio-Based Polyacrylate Alternatives with Inherent Post-Chemical Modification and Degradation Capabilities by Organic Catalysis for Polymerization of Muconate Esters.

Thomas Dardé, Émilie Diomar, Xavier Schultze, Daniel Taton

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Thomas DardéLaboratoire de Chimie des Polymères Organiques (LCPO), Université de Bordeaux, CNRS, Bordeaux INP, UMR 5629, 16 av. Pey Berland, 33607, Pessac cedex, France.
Émilie DiomarLaboratoire de Chimie des Polymères Organiques (LCPO), Université de Bordeaux, CNRS, Bordeaux INP, UMR 5629, 16 av. Pey Berland, 33607, Pessac cedex, France.
Xavier SchultzeL'Oréal Research & Innovation, 1 Avenue Eugène Schueller, 93601, Aulnay Sous-Bois, France.
Daniel TatonLaboratoire de Chimie des Polymères Organiques (LCPO), Université de Bordeaux, CNRS, Bordeaux INP, UMR 5629, 16 av. Pey Berland, 33607, Pessac cedex, France.ORCID https://orcid.org/0000-0002-8539-4963

Funding

L'Oréal contract # 220674
6 · The paper itself

Abstract

The quest for polymers that would be at the same time bio-based and degradable after usage, in addition to offering chemical post-modification options, remains a daunting challenge in contemporary polymer science. Despite advances in polymer chemistry, attempts at controlling the chain-growth polymerization of muconate esters remain unexplored. Here we show that dialkyl muconates can be rapidly polymerized by organocatalyzed group transfer polymerization (O-GTP). O-GTP is conducted to completion at room temperature in toluene within a few minutes, using 1-ethoxy-1-(trimethylsiloxy)-1,3-butadiene (ETSB) as initiator and 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2

Indexed as

Bio-based polymersDegradable polymersGroup transfer polymerizationOrganic catalysis

Identifiers

PMID39315673
PMCPMC11609888

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.