ArticleJournal of the American Chemical Society2024
Synthesis of Metal-Organic Cages via Orthogonal Bond Cleavage in 3D Metal-Organic Frameworks.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Excision in Reduced Dimensionality: Synthesis of 1D Covalent Organic Framework via Clip-off Chemistry.Angewandte Chemie (International ed. in English) · 2026Article
- Polymer-Grafted Cu(II) Metal-Organic Polyhedra as Scalable, Melt-Processable Porous Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- Porous Organic Cages as Building Blocks for Framework Materials.Angewandte Chemie (International ed. in English) · 2025Review
- Merging and Clipping Nets for the Synthesis of Three- and Two-Merged Net Metal-Organic Frameworks.Journal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Herein we address the question of whether a supramolecular finite metal-organic structure such as a cage or metal-organic polyhedron (MOP) can be synthesized via controlled cleavage of a three-dimensional (3D) metal-organic structure. To demonstrate this, we report the synthesis of a Cu(II)-based cuboctahedral MOP through orthogonal olefinic bond cleavage of the cavities of a 3D, Cu(II)-based, metal-organic framework (MOF). Additionally, we demonstrate that controlling the ozonolysis conditions used for the cleavage enables Clip-off Chemistry synthesis of two cuboctahedral MOPs that differ by their external functionalization: one in which all 24 external groups represent a mixture of aldehydes, carboxylic acids, acetals and esters, and one in which all are aldehydes.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.