Evidence map›Paper›PMID 39302690›Full record

ArticleACS nano2024

Illuminating Biomimetic Nanochannels: Unveiling Macroscopic Anticounterfeiting and Photoswitchable Ion Conductivity via Polymer Tailoring.

Yi-Fan Chen, Vaishali Pruthi, Lin-Ruei Lee, Yu-Chun Liu, Ming-Hsuan Chang, Patrick Théato, Jiun-Tai Chen

Abstract read
In one paragraph

Article in ACS nano, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Yi-Fan ChenDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, 300093 Hsinchu, Taiwan.
Vaishali PruthiInstitute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, D-76131 Karlsruhe, Germany.ORCID 0000-0002-3148-7873
Lin-Ruei LeeDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, 300093 Hsinchu, Taiwan.
Yu-Chun LiuDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, 300093 Hsinchu, Taiwan.
Ming-Hsuan ChangDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, 300093 Hsinchu, Taiwan.
Patrick ThéatoInstitute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, D-76131 Karlsruhe, Germany.ORCID 0000-0002-4562-9254
Jiun-Tai ChenDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, 300093 Hsinchu, Taiwan.ORCID 0000-0002-0662-782X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Artificial photomodulated channels represent a significant advancement toward practical photogated systems because of their remote noncontact stimulation. Ion transport behaviors in artificial photomodulated channels, however, still require further investigation, especially in multiple nanochannels that closely resemble biological structures. Herein, we present the design and development of photoswitchable ion nanochannels inspired by natural channelrhodopsins (ChRs), utilizing photoresponsive polymers grafted anodic aluminum oxide (AAO) membranes. Our approach integrates spiropyran (SP) as photoresponsive molecules into nanochannels through surface-initiated atom transfer radical polymerization (SI-ATRP), creating a responsive system that modulates ionic conductivity and hydrophilicity in response to light stimuli. A key design feature is the reversible ring-opening photoisomerization of spiropyran groups under UV irradiation. This transformation, observable at the molecular level and macroscopically, allows the surface inside the nanochannels to switch between hydrophobic and hydrophilic states, thus efficiently modulating ion transport via changing water wetting behaviors. The patternable and erasable polySP-grafted AAO, based on a controllable and reversible photochromic effect, also shows potential applications in anticounterfeiting. This study pioneers achieving macroscopic anticounterfeiting and photoinduced photoswitching through reversible surface chemistry and expands the application of polymer-grafted structures in multiple nanochannels.

Indexed as

anodic aluminum oxideanticounterfeitingbiological nanochannelion conductivityphotoswitchablespiropyran

Identifiers

PMID39302690
PMCPMC11447919

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.