ReviewAngewandte Chemie (International ed. in English)2024
Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.
Review in Angewandte Chemie (International ed. in English), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Aqueous Accumulation and Co-Accumulation of Multiple Cationic Porphyrins within a Polyaromatic Capsule.JACS Au · 2026Article
- Non-Dilute Synthesis of Macrodiolides and Macrotetrolides Enabled by Confinement Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Rational Design of Supramolecular Fe and Mn Oxidation Catalysts.Accounts of chemical research · 2026Article
- Balancing acceleration and turnover in [1 + 1] tetra-imine bis-calix[4]pyrrole reactor for Huisgen cycloadditions.Nature communications · 2026Article
- Confinement Catalysis Enables Macrocyclization at Up to 0.6 M: Selective Formation of Mono- and Dimeric Glycosidic Macrocycles.Journal of the American Chemical Society · 2026Article
- Hybridized Host Functions in Polyaromatic Tube-in-Capsule Composites.Angewandte Chemie (International ed. in English) · 2026Article
- Attractive Noncovalent Interactions versus Steric Confinement in Asymmetric Supramolecular Catalysis.Journal of the American Chemical Society · 2026Article
- Construction of Well-Defined Yet Adaptable Oligo(Amino Acid) Cavities within an Aromatic Micelle.Journal of the American Chemical Society · 2026Article
- Selective Noncovalent Catalysis with Small Molecules.Chemical reviews · 2025Review
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.Angewandte Chemie (International ed. in English) · 2024Review
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
There is increasing interest in the discovery and application of molecular flasks-supramolecular host structures capable of catalyzing organic reactions. Reminiscent of enzymes due to possessing a host cavity akin to an active site, molecular flasks can exhibit complex catalytic mechanisms and in many cases provide selectivity not achievable in bulk solvent. In this Review, we aim to organize the increasingly diverse examples through a two-part structure. In part one, we provide an overview of the different acceleration modes that operate within molecular flasks, while in part two we showcase, through selected examples, the different types of selectivity that are obtainable through the use of molecular flasks. Particular attention is given to examples that are relevant to current challenges in synthetic organic chemistry. We believe that this structure makes the field more approachable and thus will stimulate the development of novel applications of molecular flasks.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.