ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024
Revealing the Impact of Aging on Perovskite Solar Cells Employing Nickel Phthalocyanine-Based Hole Transporting Material.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Meso-Crowned Porphyrin as a Dual Cavity Hybrid Macrocycle for Improving the Efficiency and Stability of Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Zinc Metal Complex of tert-butyl Substituted Phthalocyanine: Assessment of Photosensitizer Potential with Theoretical Calculations.Journal of fluorescence · 2025Article
- Revealing the Impact of Aging on Perovskite Solar Cells Employing Nickel Phthalocyanine-Based Hole Transporting Material.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
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Authors and funding
12 authors.
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Abstract
The enhancement of the photovoltaic performance upon the aging process at particular environment is often observed in perovskite solar cells (PSCs), particularly for the devices with 2,2',7,7'-tetrakis(N,N-di(4-methoxyphenyl)amino)-9,9'-spirobifluorene (spiro-OMeTAD) as hole transporting material (HTM). In this work, for the first time the effect of aging the typical n-i-p PSCs employing nickel phthalocyanine (coded as Bis-PF-Ni) solely as dopant-free HTM is investigated and as an additive in spiro-OMeTAD solution. This study reveals that the prolong aging of these devices at dry air condition (RH = 2%, 25 °C) is beneficial for the improvement of their performances. Various bulk and surface characterization techniques are utilized to understand the factors behind the spontaneous efficiency enhancement of the devices after storage. As a result, the changes in properties of the Bis-PF-Ni layer are observed and at perovskite/Bis-PF-Ni interface, which ultimately improves the charge transport and reduces non-radiative recombination. In addition, the devices with Bis-PF-Ni HTM reveal enhanced long-term ambient and thermal stability compared to the PSCs based on doped spiro-OMeTAD.
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