ArticleJournal of the American Chemical Society2024
Mix and Match Tuning of the Conformational and Multistate Redox Switching Properties of an Overcrowded Alkene.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Protonation-Gated Orthogonal Control of Highly Efficient Molecular Motors With Broad Visible-Light Responsiveness.Angewandte Chemie (International ed. in English) · 2026Article
- Organocatalytic asymmetric synthesis of atropisomeric tetraarylethenes: design, properties, and applications.Chemical science · 2026Article
- Overcrowded Alkene Photo-Redox-Switches Based on Quinolinium/Carbene Building Blocks.Angewandte Chemie (International ed. in English) · 2026Article
- Lucigenin: a strongly oxidizing dicationic photocatalyst for the direct azolation of arenes.Chemical science · 2026Article
- Complex and Unusual Excited-State Relaxation Dynamics of 9,9'-Bifluorenylidene Revealed by Comprehensive Time-Resolved Spectroscopy and MRSF-TDDFT Calculations.The journal of physical chemistry letters · 2026Article
- Multi-Stimulus Triggered Programmable Transformation of Molecular Motor Based Chiral Supramolecular Polymers in Water.Angewandte Chemie (International ed. in English) · 2026Article
- Light-gated redox switching and actuation in polymer hydrogels.Nature communications · 2025Article
- Multi-State Redox and Light-Driven Switching of Pseudorotaxanation and Cation Shuttling.Journal of the American Chemical Society · 2025Article
- Multiple Near-Infrared Chromisms of a Heteromerous Overcrowded Ethylene with Large Permanent Dipole Moment.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Overcrowded alkenes have received considerable attention as versatile structural motifs in a range of optical switches and light-driven unidirectional motors. In contrast, their actuation by electrochemical stimuli remains underexplored, even though this alternative energy input may be preferred in various applications and enables additional control over molecular switching states and properties. While symmetric bistricyclic overcrowded enes (BAEs) containing two identical halves based on either thioxanthene (TX) or acridine (Acr) motifs are known to be reversible conformational redox switches, their redox potentials are generally too high or low, respectively, thereby preventing wider applications. Herein, we demonstrate that the "mixed" TX-Acr switch possesses redox properties that lie between those of its parent symmetric analogs, enabling interconversion between three stable redox and conformational states at mild potentials. This includes the neutral
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.