Evidence map›Paper›PMID 39271695›Full record

ArticleNature communications2024

Designing neighboring-site activation of single atom via tunnel ions for boosting acidic oxygen evolution.

Yixin Hao, Sung-Fu Hung, Luqi Wang, Liming Deng, Wen-Jing Zeng, Chenchen Zhang, Zih-Yi Lin, Chun-Han Kuo, Ye Wang, Ying Zhang and 4 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Review
  3. Oxygen Evolution Reaction Catalysts for Acidic-Media COAdvanced materials (Deerfield Beach, Fla.) · 2026
    Review
  4. Article
  5. Article
  6. Article
  7. Co-Motif-Engineered RuOACS applied materials & interfaces · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Yixin HaoCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Sung-Fu HungDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 300, Taiwan.ORCID http://orcid.org/0000-0002-7423-2723
Luqi WangCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Liming DengCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Wen-Jing ZengDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 300, Taiwan.ORCID http://orcid.org/0009-0000-3342-5396
Chenchen ZhangKey Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, Jiangsu, China.
Zih-Yi LinDepartment of Applied Chemistry, National Yang Ming Chiao Tung University, Hsinchu, 300, Taiwan.
Chun-Han KuoDepartment of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan.
Ye WangCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Ying ZhangKey Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, Jiangsu, China.ORCID http://orcid.org/0000-0001-6394-3231
Han-Yi ChenDepartment of Materials Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan.ORCID http://orcid.org/0000-0001-8146-7101
Feng HuCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Linlin LiCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China.
Shengjie PengCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 210016, Nanjing, China. pengshengjie@nuaa.edu.cn.ORCID http://orcid.org/0000-0003-1591-1301

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22075141National Natural Science Foundation of China (National Science Foundation of China) 22101132
6 · The paper itself

Abstract

Realizing an efficient turnover frequency in the acidic oxygen evolution reaction by modifying the reaction configuration is crucial in designing high-performance single-atom catalysts. Here, we report a "single atom-double site" concept, which involves an activatable inert manganese atom redox chemistry in a single-atom Ru-Mn dual-site platform with tunnel Ni ions as the trigger. In contrast to conventional single-atom catalysts, the proposed configuration allows direct intramolecular oxygen coupling driven by the Ni ions intercalation effect, bypassing the secondary deprotonation step instead of the kinetically sluggish adsorbate evolution mechanism. The strong bonding of Ni ions activates the inert manganese terminal groups and inhibits the cross-site disproportionation process inherent in the Mn scaffolding, which is crucial to ensure the dual-site platform. As a result, the single-atom Ru-Ni-Mn octahedral molecular sieves catalyst delivers a low overpotential, adequate mass activity and good stability.

Identifiers

PMID39271695
PMCPMC11399115

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.