Boosting of Redox-Active Polyimide Porous Organic Polymers with Multi-Walled Carbon Nanotubes towards Pseudocapacitive Energy Storage.

Tian Zhou, Yu Yuan, Luyi Xiao, Wei Ding, Yong Wang, Li-Ping Lv

Abstract read

In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

6 authors.

Tian ZhouSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.

Yu YuanSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.

Luyi XiaoSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.

Wei DingSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.

Yong WangSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.ORCID 0000-0003-3489-7672

Li-Ping LvSchool of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China.ORCID 0000-0003-4054-008X

Funding

National Natural Science Foundation of China 22279078National Natural Science Foundation of China 52073170Shanghai Municipal Education Commission 2019-01-07-00-09-E00021

6 · The paper itself

Abstract

Redox-active porous organic polymers (POPs) demonstrate significant potential in supercapacitors. However, their intrinsic low electrical conductivity and stacking tendencies often lead to low utilization rates of redox-active sites within their structural units. Herein, polyimide POPs (donated as PMTA) are synthesized in situ on multi-walled carbon nanotubes (MWCNTs) from tetramino-benzoquinone (TABQ) and 1,4,5,8-naphthalene tetracarboxylic dianhydride (PMDA) monomers. The strong π-π stacking interactions drive the PMTA POPs and the MWCNTs together to form a PMTA/MWCNT composite. With the assistance of MWCNTs, the stacking issue and low conductivity of PMTA POPs are well addressed, leading to the obvious activation and enhanced utilization of the redox-active groups in the PMTA POPs. PMTA/MWCNT then achieves a high capacitance of 375.2 F g

Indexed as

multi-walled carbon nanotubespolyimideporous organic polymerspseudocapacitanceredox-active polymers

Identifiers

PMID39269050

DOI10.3390/nano14171388

PMCPMC11397463

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.