ArticleThe journal of physical chemistry. C, Nanomaterials and interfaces2024
From Precious to Earth-Abundant Metallic Nanoparticles: A Trend of Interband Transitions in Photocatalyzed Nitrobenzene Reduction.
Article in The journal of physical chemistry. C, Nanomaterials and interfaces, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Deciphering the Photocatalysis Mechanism of Semimetallic Bismuth Nanoparticles.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
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Authors and funding
4 authors.
Funding
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Abstract
Metallic nanoparticles have been demonstrated to be versatile photocatalysts, as exemplified by those made from noble and precious metals. Transitioning from precious to earth-abundant metals for sustainable photocatalysis requires benchmarking their catalytic performance. In this work, we attempt to compare the photocatalytic activities of Au, Pd, and Co-B nanoparticles in the reduction of nitrobenzene by hydrazine. Despite their different morphologies and surface structures, Co-B nanoparticles offer the highest catalytic enhancement when comparing their reaction rates under irradiation to those under nonirradiation conditions. The trend of improved photocatalytic performance when transitioning from Au to Pd, and then to Co-B, can be explained by the nature of their d-band positions and corresponding hot carriers photogenerated from interband transitions.
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Registered trials
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