Evidence map›Paper›PMID 39251614›Full record

ArticleNature communications2024

Rational design of metal-organic cages to increase the number of components via dihedral angle control.

Tsukasa Abe, Keisuke Takeuchi, Masahiro Higashi, Hirofumi Sato, Shuichi Hiraoka

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Reduced Symmetry Metal-Organic Cage-to-Framework Materials.Angewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Article
  5. Formation of a PdJACS Au · 2025
    Article
  6. Article
  7. Synergistic regulation of metal-organic cage architectures via temperature- and solvent-driven atropisomerism.Proceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  8. Mechanical interlocking of metal organic cages.Communications chemistry · 2025
    Review
  9. Template and Solid-State-Assisted Assembly of an MJournal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Tsukasa AbeDepartment of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Tokyo, 153-8902, Japan.ORCID http://orcid.org/0000-0002-2400-3797
Keisuke TakeuchiDepartment of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Tokyo, 153-8902, Japan.ORCID http://orcid.org/0009-0002-9038-9517
Masahiro HigashiDepartment of Complex Systems Science, Graduate School of Informatics, Nagoya University, Nagoya, 464-8601, Japan.ORCID http://orcid.org/0000-0001-9829-389X
Hirofumi SatoDepartment of Molecular Engineering, Kyoto University, Kyoto, 615-8510, Japan.ORCID http://orcid.org/0000-0001-6266-9058
Shuichi HiraokaDepartment of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Tokyo, 153-8902, Japan. hiraoka-s@g.ecc.u-tokyo.ac.jp.ORCID http://orcid.org/0000-0002-9262-4747

Funding

Asahi Glass Foundation noneMEXT | Japan Society for the Promotion of Science (JSPS) 21K18974MEXT | Japan Society for the Promotion of Science (JSPS) 23H01970
6 · The paper itself

Abstract

The general principles of discrete, large self-assemblies composed of numerous components are not unveiled and the artificial formation of such entities is a challenging topic. In metal-organic cages, design strategies for tuning the coordination directions in multitopic ligands by the bend and twist angles were previously developed to solve this problem. In this study, the importance of remote geometric communications between components is emphasized, realizing several types of metal-organic assemblies based on dihedral angle control in multitopic ligands although they have the same coordination directions. Self-assembly of a tritopic ligand with dihedral angles θ = 36.5° and a cis-protected Pd(II) ion affords M

Identifiers

PMID39251614
PMCPMC11383860

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.