ArticleJournal of the American Chemical Society2024
The Counterintuitive Relationship between Orbital Energy, Orbital Overlap, and Bond Covalency in CeF
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
5 citing papers in PubMed.
- Single-Determinant Ground State in CeInorganic chemistry · 2025Article
- Isolation of Ce(iv) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency.Chemical science · 2025Article
- Flash Communication: Boron K‑edge XAS and TDDFT Studies of Covalent Metal-Ligand Bonding in Ni(COrganometallics · 2025Article
- Developing a Rate Law for Ce(III) Oxidation by Manganese Oxides.Environmental science & technology · 2025Article
- Tuning the Electronic Properties of Tetravalent Cerium Complexes via Ligand Derivatization.Inorganic chemistry · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The 4f orbitals of Ce(IV) have shown appreciably enhanced covalent mixing with ligand orbitals relative to those of Ce(III). Here, X-ray spectroscopy, magnetic susceptibility measurements, and theoretical methods are used to investigate 4f covalency in CeF
Identifiers
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Registered trials
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