ArticleAngewandte Chemie (International ed. in English)2025
Light- and Temperature-Controlled Hybridization, Chiral Induction and Handedness of Helical Foldamers.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Multivalent-Anion-Induced Inversion of Chiroptical Signals in a Cyanine Dye Bound to Nanotubular Supramolecular Assemblies.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Temperature‑, Concentration‑, and Solvent-DependentJACS Au · 2026Article
- Electroactive Foldamers Endowed with Tetrathiafulvalene Units: From Highly Stable Single Helical Structures to Redox-Triggered Duplex Formation.Chemistry, an Asian journal · 2025Article
- Photoresponsive Helical Foldamers: Conformational Control Through Double Helix Formation and Light-Induced Protonation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Light- and Temperature-Controlled Hybridization, Chiral Induction and Handedness of Helical Foldamers.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
11 authors.
Funding
Abstract
Helical foldamers have attracted much attention over the last decades given their resemblance to certain biomacromolecules and their potential in domains as different as pharmaceutics, catalysis and photonics. Various research groups have successfully controlled the right- or left- handedness of these oligomers by introducing stereogenic centers through covalent or non-covalent chemistry. However, developing helical structures whose handedness can be reversibly switched remains a major challenge for chemists. To date, such an achievement has been reported with light-responsive single-stranded foldamers only. Herein, we demonstrate that grafting a unidirectional motor onto foldamer strands constitutes a relevant strategy to i) control the single or double helical state of a foldamer, ii) switch on the chiral induction process from the motor to the helical strands and iii) select the handedness of double helical structures through photochemical and thermal stimulations.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.