ArticleBeilstein journal of organic chemistry2024
Efficacy of radical reactions of isocyanides with heteroatom radicals in organic synthesis.
Article in Beilstein journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Non-innocent behaviour of aromatic isocyanides under visible light: a pathway to thioformimidates and dehydroalanine.Chemical science · 2026Article
- Modern radical chemistry.Beilstein journal of organic chemistry · 2025Article
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Authors and funding
2 authors.
Funding
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Abstract
Isocyanide is a promising synthetic reagent not only as a one-carbon homologation reagent but also as a nitrogen source for nitrogen-containing molecules. Because of their isoelectronic structure with carbon monoxide, isocyanides also react with nucleophiles, electrophiles, carbon radicals, and transition metal reagents, and are widely used in organic synthesis. On the other hand, the use of isocyanides in reactions with heteroatom radicals is limited. However, the reaction of isocyanides with heteroatom radicals is a promising synthetic tool for the construction of nitrogen-containing organic molecules modified with a variety of heteroatoms. In this Perspective, we review the addition and cyclization reactions of heteroatom radicals with isocyanides and discuss the synthetic prospects of the reaction of isocyanides with heteroatom radicals.
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