ArticleNature communications2024
Co-adsorbed self-assembled monolayer enables high-performance perovskite and organic solar cells.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 56 papers.
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Who cites it
56 citing papers in PubMed.
- Amine-rich cross-linking templates enabling toughened self-assembled monolayer for stable perovskite solar modules.Science advances · 2026Article
- Interfacial Enhancement of Self-Assembled Monolayer by Thermal Annealing and its Impact on Perovskite Solar Cells.ChemSusChem · 2026Article
- Perylenocarbazole-Based Polycyclic Aromatic Self-Assembled Monolayers with Tailored Electrostatic Potentials for High-Performance Organic and Perovskite Solar Cells.Angewandte Chemie (International ed. in English) · 2026Article
- Minimal Input, Maximum Insight: Inferring Material Parameters From Solar Cell JV Curves Alone.Small methods · 2026Article
- Navigating Molecular Structures of Self-Assembled Monolayers for High Efficiency Perovskite Photovoltaics.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Dipole-engineered co-adsorbed self-assembled monolayers boost Cs-based inorganic Pb-Sn perovskite tandem efficiency beyond 20.Nature communications · 2026Article
- Molecular Engineering of Ionization-Responsive Self-Assembled Hole-Transport Materials for High-Performance Inverted Perovskite Solar Cells.Organic letters · 2026Article
- Symmetry-breaking co-assembly of conjugated molecules boosts perovskite photovoltaics.Nature communications · 2026Article
- Stacking-order-driven interfacial dipole flip and chlorine-iodine exchange for high-performance perovskite-organic tandem solar cells.Nature communications · 2026Article
- Interfacial Engineering Strategies of Self-Assembled Monolayers for Inverted Perovskite Solar Cells.Nanomaterials (Basel, Switzerland) · 2026Review
- Aggregation-Induced Doping Enhancement Enabled by Non-Covalent Conformation Locking on Conjugated Polyelectrolyte Toward Efficient Hole Collection in Organic Solar Cells.Angewandte Chemie (International ed. in English) · 2026Article
- Layered Defect-Filling co-Assembled Carbazole-Based SAMs Deliver 20% Organic Solar Cells and 17% Mini-Modules.Nano-micro letters · 2026Article
- Non-competitive additives regulate molecular assembly for compact monolayers in perovskite/silicon tandems.Nature communications · 2026Article
- 21.26% Efficiency Organic Solar Cells Enabled by Mixed Self-Assembled Multilayers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Data-Driven Design of Self-Assembled Monolayers for High-Efficiency Perovskite Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Co-Assembled Hybrid Interlayer Engineering for Enhanced Upper Interface Stability in Inverted Perovskite Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Noncoplanar multidentate contacts reinforce buried interface for perovskite/silicon tandem solar cells.Science advances · 2026Article
- Soft supermolecule stabilized buried interface for high-performance inverted perovskite solar cells and modules.Nature communications · 2026Article
- Unlocking 27.3% perovskite photovoltaics by interface-locked dual-molecule contact.Science advances · 2026Article
- A Flexible Side-Chain Dispersant Enables Uniform Self-Assembled Monolayers for 18.67% Organic Solar Cells.Molecules (Basel, Switzerland) · 2026Article
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Authors and funding
18 authors.
Funding
Abstract
Self-assembled monolayers (SAMs) have become pivotal in achieving high-performance perovskite solar cells (PSCs) and organic solar cells (OSCs) by significantly minimizing interfacial energy losses. In this study, we propose a co-adsorb (CA) strategy employing a novel small molecule, 2-chloro-5-(trifluoromethyl)isonicotinic acid (PyCA-3F), introducing at the buried interface between 2PACz and the perovskite/organic layers. This approach effectively diminishes 2PACz's aggregation, enhancing surface smoothness and increasing work function for the modified SAM layer, thereby providing a flattened buried interface with a favorable heterointerface for perovskite. The resultant improvements in crystallinity, minimized trap states, and augmented hole extraction and transfer capabilities have propelled power conversion efficiencies (PCEs) beyond 25% in PSCs with a p-i-n structure (certified at 24.68%). OSCs employing the CA strategy achieve remarkable PCEs of 19.51% based on PM1:PTQ10:m-BTP-PhC6 photoactive system. Notably, universal improvements have also been achieved for the other two popular OSC systems. After a 1000-hour maximal power point tracking, the encapsulated PSCs and OSCs retain approximately 90% and 80% of their initial PCEs, respectively. This work introduces a facile, rational, and effective method to enhance the performance of SAMs, realizing efficiency breakthroughs in both PSCs and OSCs with a favorable p-i-n device structure, along with improved operational stability.
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