Evidence map›Paper›PMID 39183902›Full record

ArticleChemical science2024

Construction of intermolecular σ-hole interactions in rare earth metallocene complexes using a 2,3,4,5-tetraiodopyrrolyl anion.

Francis Delano, Florian Benner, Seoyun Jang, Samuel M Greer, Selvan Demir

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Francis DelanoDepartment of Chemistry, Michigan State University 578 South Shaw Lane East Lansing Michigan 48824 USA sdemir@chemistry.msu.edu.ORCID https://orcid.org/0000-0002-7509-4502
Florian BennerDepartment of Chemistry, Michigan State University 578 South Shaw Lane East Lansing Michigan 48824 USA sdemir@chemistry.msu.edu.ORCID https://orcid.org/0000-0002-8489-566X
Seoyun JangDepartment of Chemistry, Michigan State University 578 South Shaw Lane East Lansing Michigan 48824 USA sdemir@chemistry.msu.edu.ORCID https://orcid.org/0000-0002-1651-6883
Samuel M GreerLos Alamos National Laboratory (LANL) Los Alamos New Mexico 87545 USA.ORCID https://orcid.org/0000-0001-8225-3252
Selvan DemirDepartment of Chemistry, Michigan State University 578 South Shaw Lane East Lansing Michigan 48824 USA sdemir@chemistry.msu.edu.ORCID https://orcid.org/0000-0001-7983-9850

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The generation of noncovalent intermolecular interactions represents a powerful method to control molecular vibrations and rotations. Combining these with the axial ligand field enforced by the metallocene ligand scaffold provides a dual-pronged approach in controlling the magnetic-relaxation pathways for dysprosium-based single-molecule magnets (SMMs). Here, we present the first implementation of 2,3,4,5-tetraiodopyrrole (TIPH) in its anionic form [TIP]

Identifiers

PMID39183902
PMCPMC11339973

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.