ReviewNature reviews. Chemistry2024
Understanding covalency in molecular f-block compounds from the synergy of spectroscopy and quantum chemistry.
Review in Nature reviews. Chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Equatorial thiolate ligand effects in polynuclear dysprosium metallocene single-molecule magnets.Inorganic chemistry frontiers · 2026Article
- Electron Affinity of Actinide (IV) Carboxylate Complexes From MN12-L Density-Functional Calculations and Explainable Machine Learning.Journal of computational chemistry · 2026Article
- Resolving the innerChemical science · 2026Article
- Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.Journal of the American Chemical Society · 2026Article
- Chiral LiPS-LiTFSI dimers enabling biomimetic electrocatalysis in lithium||sulfur batteries.Nature communications · 2026Article
- Elucidating metal (Zr, Hf, Th, U)-hydride covalency usingCommunications chemistry · 2026Article
- Oxidation State Dependence of the Actinide MInorganic chemistry · 2026Article
- Anion-mediated solvation structures and intercalation chemistry of aqueous zinc-ion electrolytes.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- f-Block Element-Based MOF Thin Films: A Platform for Luminescence, Sensing, and Energy Applications.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Determination of Magnetic Anisotropy Tensors in Actinide Complexes Using Torque Magnetometry: A U(IV) Case Study.Journal of the American Chemical Society · 2026Article
- Balance between Crystal Field and Phonon Optimization in Defining the Magnetic Properties of Lanthanide Dichalcogenoimidodiphosphinate Complexes.Inorganic chemistry · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
One of the most intensely studied areas of f-block chemistry is the nature of the bonds between the f-element and another species, and in particular the role played by covalency. Computational quantum chemical methods have been at the forefront of this research for decades and have a particularly valuable role, given the radioactivity of the actinide series. The very strong agreement that has recently emerged between theory and the results of a range of spectroscopic techniques not only facilitates deeper insight into the experimental data, but it also provides confidence in the conclusions from the computational studies. These synergies are shining new light on the nature of the f element-other element bond.
Identifiers
39174633What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.