ArticleChemSusChem2024
Azolium-Porphyrin Electrosynthesis.
Article in ChemSusChem, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Azolium-Porphyrin Electrosynthesis.ChemSusChem · 2024Article
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Authors and funding
12 authors.
Funding
Abstract
Electrochemical oxidation of Zn(II) 2,7,12,17-tetra-tert-butylporphyrin in the presence of a series of azole derivatives (1-methylimidazole, 1-vinyl-1H-imidazole, 2-(1H-imidazol-1-yl)pyridine, 1-methylbenzimidazole, 1-methyl-1H-1,2,4-triazole, and benzothiazole) affords the corresponding meso-substituted azolium-porphyrins in very mild conditions and good yields. It was found that these nucleophiles were strongly ligated to the zinc(II) azolium-porphyrin complexes. Thus a demetalation/remetalation procedure was performed to recover the non-azole-coordinated zinc(II) complexes. X-ray crystallographic structures of three azolium-porphyrins were solved. Cyclic voltammetry analyses provided insight into the electron-withdrawing effect of the azolium substituents.
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Registered trials
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