Evidence map›Paper›PMID 39169910›Full record

ReviewACS catalysis2024

Design and Impact: Navigating the Electrochemical Characterization Methods for Supported Catalysts.

Karl-Ander Kasuk, Jaak Nerut, Vitali Grozovski, Enn Lust, Anthony Kucernak

Abstract readReview
In one paragraph

Review in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Karl-Ander KasukInstitute of Chemistry, University of Tartu, Ravila 14a, 50411 Tartu, Estonia.ORCID https://orcid.org/0000-0002-1858-912X
Jaak NerutInstitute of Chemistry, University of Tartu, Ravila 14a, 50411 Tartu, Estonia.ORCID https://orcid.org/0000-0001-9153-4478
Vitali GrozovskiInstitute of Chemistry, University of Tartu, Ravila 14a, 50411 Tartu, Estonia.
Enn LustInstitute of Chemistry, University of Tartu, Ravila 14a, 50411 Tartu, Estonia.
Anthony KucernakDepartment of Chemistry, Imperial College London, 80 Wood Lane, W12 7TA London, United Kingdom.ORCID https://orcid.org/0000-0002-5790-9683

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This review will investigate the impact of electrochemical characterization method design choices on intrinsic catalyst activity measurements by predominantly using the oxygen reduction reaction (ORR) on supported catalysts as a model reaction. The wider use of hydrogen for transportation or electrical grid stabilization requires improvements in proton exchange membrane fuel cell (PEMFC) performance. One of the areas for improvement is the (ORR) catalyst efficiency and durability. Research and development of the traditional platinum-based catalysts have commonly been performed using rotating disk electrodes (RDE), rotating ring disk electrodes (RRDE), and membrane electrode assemblies (MEAs). However, the mass transport conditions of RDE and RRDE limit their usefulness in characterizing supported catalysts at high current densities, and MEA characterizations can be complex, lengthy, and costly. Ultramicroelectrode with a catalyst-filled cavity addresses some of these problems, but with limited success. Due to the properties discussed in this review, the recent floating electrode (FE) and the gas diffusion electrode (GDE) methods offer additional capabilities in the electrochemical characterization process. With the FE technique, the intrinsic activity of catalysts for ORR can be investigated, leading to a better understanding of the ORR mechanism through more reliable experimental data from application-relevant high-mass transport conditions. The GDEs are helpful bridging tools between RDE and MEA experiments, simplifying the fuel cell and electrolyzer manufacturing and operating optimization process.

Identifiers

PMID39169910
PMCPMC11334114

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.