ArticleNature communications2024
Cairo pentagon tessellated covalent organic frameworks with mcm topology for near-infrared phototherapy.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- 2D nanomaterials for near infrared responsive photomedicine: a review.Nano convergence · 2026Review
- Electronic Modulation of Flexible Ether Oxygen-Based Covalent Organic Frameworks for Efficient Oxygen Reduction Reaction.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Sulfonated Ionic Covalent Organic Frameworks With Dual-State Activation for Synergistic Photodynamic-Ferroptosis Therapy.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Deep Learning Assisted Heteroporous Covalent Organic Framework Hydrogels Enable Dual-Mode Tracking and Analysis to Parkinson's Management.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- A synergistic strategy of AIE and electron asymmetry anchored in covalent organic frameworks for enhanced periodontitis photodynamic therapy.Materials today. Bio · 2026Article
- In Situ Synthesis of Covalent Organic Frameworks Inside Cells for Triggering Ferroptosis and Immunotherapy.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Structural Engineering of Photoisomerizable Covalent Organic Frameworks: Design Principles and Functional Applications.Polymer science & technology (Washington, D.C.) · 2025Review
- Evidence of Heteroepitaxy and Solid Solutions in Lattice Matched Ternary Covalent Organic Framework Systems.Journal of the American Chemical Society · 2025Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Despite the prevalent of hexagonal, tetragonal, and triangular pore structures in two-dimensional covalent organic frameworks (2D COFs), the pentagonal pores remain conspicuously absent. We herein present the Cairo pentagonal tessellated COFs, achieved through precisely chosen geometry and metrics of the linkers, resulting in unprecedented mcm topology. In each pentagonal structure, porphyrin units create four uniform sides around 15.5 Å with 90° angles, while tetrabiphenyl unit establish a bottom edge about 11.6 Å with 120° angles, aligning precisely with the criteria of Cairo Pentagon. According to the narrow bandgap and strong near-infrared (NIR) absorbance, as-synthesized COFs exhibit the efficient singlet oxygen (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.