ArticleJournal of the American Chemical Society2024
An Azide-Free Synthesis of Metallodiazomethanes Using Nitrous Oxide.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Isolable C-Phosphonio-Boratavinyl Anion.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis, structural analysis and reactivity of alkynyl sulfide anions.Inorganic chemistry frontiers · 2026Article
- Activation of NDalton transactions (Cambridge, England : 2003) · 2026Article
- Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides.Angewandte Chemie (International ed. in English) · 2026Article
- Direct diazotization of indoles with 2-Methoxyethyl nitrite.Communications chemistry · 2026Article
- Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
- PhAngewandte Chemie (International ed. in English) · 2025Article
- Distinct Difference in the Geometries of NCCLInorganic chemistry · 2025Article
- Covalent capture of nitrous oxide by phosphanides.Chemical communications (Cambridge, England) · 2025Article
- Rethinking carbanion chemistry from donor substituents to weakly coordinating carbanions.Nature reviews. Chemistry · 2025Review
- PPhAngewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Diazo compounds are valuable reagents in synthesis but usually require the use of potentially explosive or toxic starting materials. Here, we report the synthesis and isolation of alkali metal diazomethanides by the reaction of metalated ylides with nitrous oxide, resulting in a formal exchange of the phosphine ligand by dinitrogen. The reaction proceeds through a Wittig-like mechanism via a [3 + 2] cycloaddition of N
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Registered trials
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