ArticleJournal of the American Chemical Society2024
Chiroptically Active Host-Guest Composites Using a Terpene-Based Micellar Capsule.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Non-Covalent PL, CD, and CPL Activation of Linear Aromatic Oligomers within Axially Chiral Aromatic Capsules.Angewandte Chemie (International ed. in English) · 2026Article
- Aqueous Accumulation and Co-Accumulation of Multiple Cationic Porphyrins within a Polyaromatic Capsule.JACS Au · 2026Article
- Chiral Micellar Assemblies for Circularly Polarized Luminescence Amplification, Dye Encapsulation, and Multilevel Information Encryption.Angewandte Chemie (International ed. in English) · 2026Article
- Cavity Constriction and Chiralization of Polyaromatic Subnanotubes via Post-assembly Ligand/Metal Modification.Journal of the American Chemical Society · 2026Article
- Chiral Aromatic Micelles as Chiroptical Host Tools for Large Metallodyes in Water.Journal of the American Chemical Society · 2025Article
- Optical Axial Chirality Enhancement and Transfer within Aromatic Micelles upon (Co-)encapsulation.JACS Au · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
For the design of a new chiroptically active host-guest system, a bent amphiphilic compound was synthesized using cyclic monoterpenes as key biorelated chiral frameworks. In water, the bent amphiphiles form a terpene-based micellar capsule with a core diameter of ∼2 nm in a spontaneous and quantitative fashion. The resultant chiral capsule shows wide-ranging uptake abilities toward achiral fluorescent dyes in water. Notably, relatively strong CD bands are generated from the resultant host-guest composites, e.g., possessing AIE-active tetraphenylethene and sterically demanding BODIPY dyes, through efficient host-to-guest chirality transfer. The composites also display CPL, with moderate to high emission asymmetry factors (|
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Registered trials
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