Evidence map›Paper›PMID 39148804›Full record

ArticleChemical science2024

Sulfur oxidation states manipulate excited state electronic configurations for constructing highly efficient organic type I photosensitizers.

Jianye Gong, Xiaopeng Wang, Weijing Zhang, Yifan Wu, Kai Li, Renmanduhu Sha, Lingxiu Liu, Chunbin Li, Lina Feng, Guoyu Jiang and 2 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Jianye GongInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Xiaopeng WangXi'an Modern Chemistry Research Institute Xi'an 710069 P. R. China.ORCID https://orcid.org/0000-0002-4220-8737
Weijing ZhangInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Yifan WuInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Kai LiInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Renmanduhu ShaInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Lingxiu LiuInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Chunbin LiInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Lina FengInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.
Guoyu JiangInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.ORCID https://orcid.org/0000-0002-7418-889X
Jianguo WangInner Mongolia Key Laboratory of Fine Organic Synthesis Department, College of Chemistry and Chemical Engineering, Inner Mongolia University Hohhot 010021 P. R. China wangjg@iccas.ac.cn.ORCID https://orcid.org/0000-0003-0984-9716
Ben Zhong TangSchool of Science and Engineering, Shenzhen Institute of Aggregate Science and Technology, The Chinese University of Hong Kong, Shenzhen Shenzhen Guangdong 518172 P. R. China.ORCID https://orcid.org/0000-0002-0293-964X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The multiple relaxation processes of excited states are a bridge connecting molecular structures and properties, providing enormous application potential for organic luminogens. However, a systematic understanding and manipulation of the relationship between the molecular structure, excited state relaxation processes, and properties of organic luminogens is still lacking. Herein, we report a strategy for manipulating excited state electronic configurations through the regulation of the sulfur oxidation state to construct eminent organic type I PSs. Combined with the experimental results and theoretical calculations, we have successfully revealed the decisive role of high sulfur oxidation states in promoting ROS production capacity. Impressively, a higher sulfur oxidation state can reduce the singlet-triplet energy gap (Δ

Identifiers

PMID39148804
PMCPMC11322962

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.