Evidence map›Paper›PMID 39148775›Full record

ArticleChemical science2024

Understanding and tuning the electronic structure of pentalenides.

Niko A Jenek, Andreas Helbig, Stuart M Boyt, Mandeep Kaur, Hugh J Sanderson, Shaun B Reeksting, Gabriele Kociok-Köhn, Holger Helten, Ulrich Hintermair

Abstract read
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In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Niko A JenekDepartment of Chemistry, University of Bath Claverton Down Bath BA2 7AY UK u.hintermair@bath.ac.uk.ORCID https://orcid.org/0000-0002-7613-1838
Andreas HelbigInstitute of Inorganic Chemistry, Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg Am Hubland D-97074 Würzburg Germany holger.helten@uni-wuerzburg.de.
Stuart M BoytDepartment of Chemistry, University of Bath Claverton Down Bath BA2 7AY UK u.hintermair@bath.ac.uk.ORCID https://orcid.org/0000-0001-5540-0579
Mandeep KaurDepartment of Chemistry, University of Bath Claverton Down Bath BA2 7AY UK u.hintermair@bath.ac.uk.ORCID https://orcid.org/0000-0003-3376-7155
Hugh J SandersonDepartment of Chemistry, University of Bath Claverton Down Bath BA2 7AY UK u.hintermair@bath.ac.uk.ORCID https://orcid.org/0000-0002-5806-8898
Shaun B ReekstingChemical Characterisation Facility, University of Bath Claverton Down Bath BA2 7AY UK.ORCID https://orcid.org/0000-0002-6617-8210
Gabriele Kociok-KöhnChemical Characterisation Facility, University of Bath Claverton Down Bath BA2 7AY UK.ORCID https://orcid.org/0000-0002-7186-1399
Holger HeltenInstitute of Inorganic Chemistry, Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg Am Hubland D-97074 Würzburg Germany holger.helten@uni-wuerzburg.de.ORCID https://orcid.org/0000-0003-1273-3685
Ulrich HintermairDepartment of Chemistry, University of Bath Claverton Down Bath BA2 7AY UK u.hintermair@bath.ac.uk.ORCID https://orcid.org/0000-0001-6213-378X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here we report the first example of systematic tuning of the electronic properties of dianionic pentalenides through a straightforward synthetic protocol which allows the controlled variation of substituents in the 1,3,4,6-positions to produce nine new compounds, representing the largest pentalenide study to date. Both electron-withdrawing as well as electron-donating aromatics have been incorporated to achieve different polarisations of the bicyclic 10π aromatic core as indicated by characteristic

Identifiers

PMID39148775
PMCPMC11323301

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.