Evidence map›Paper›PMID 39139987›Full record

ArticleJournal of chemical and engineering data2024

Densities, Viscosities, and Self-Diffusion Coefficients of Octan-1-ol and Related Ether-Alcohols.

Markus M Hoffmann, Anthony A Gonzalez, Mandy T Huynh, Kashane K Miller, Torsten Gutmann, Gerd Buntkowsky

Abstract read
In one paragraph

Article in Journal of chemical and engineering data, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. NMR and MD Simulations of Non-Ionic Surfactants.Molecules (Basel, Switzerland) · 2025
    Review
  3. Thermal Behavior ofJournal of chemical and engineering data · 2025
    Article
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Markus M HoffmannDepartment of Chemistry and Biochemistry, State University of New York Brockport, Brockport, New York 14420, United States.ORCID https://orcid.org/0000-0002-5469-8665
Anthony A GonzalezDepartment of Chemistry and Biochemistry, State University of New York Brockport, Brockport, New York 14420, United States.
Mandy T HuynhDepartment of Chemistry and Biochemistry, State University of New York Brockport, Brockport, New York 14420, United States.
Kashane K MillerDepartment of Chemistry and Biochemistry, State University of New York Brockport, Brockport, New York 14420, United States.
Torsten GutmannInstitute of Physical Chemistry, Technical University Darmstadt, Peter-Grünberg-Straße 8, D-64287 Darmstadt, Germany.ORCID https://orcid.org/0000-0001-6214-2272
Gerd BuntkowskyInstitute of Physical Chemistry, Technical University Darmstadt, Peter-Grünberg-Straße 8, D-64287 Darmstadt, Germany.ORCID https://orcid.org/0000-0003-1304-9762

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Density, viscosity, and self-diffusion coefficients are reported for octan-1-ol and the related ether-alcohols 2-pentoxy-ethan-1-ol, 3-butoxypropan-1-ol, 4-propoxybutan-1-ol, 5-ethoxypentan-1-ol, and 6-methoxyhexan-1-ol covering temperature ranges from 298.15 to 359.15 K. These new data reveal structure-property relationships affected by the presence and the position of the ether moiety in the molecular structure of the ether-alcohols. Compared to octan-1-ol, the presence of the ether moiety causes an increase in intermolecular hydrogen bonding interactions, resulting in higher densities. The increase in density is less pronounced for those ether-octanols that engage in intramolecular hydrogen bonding. As for the effects of the ether moiety on the dynamics, these are generally faster for the ether-alcohols compared to octan-1-ol, suggesting that hydrogen bonding between ether oxygen and hydroxy hydrogen is weaker compared to hydrogen bonding between two hydroxy groups. The activation energies obtained from an Arrhenius analysis are higher for translational motion than for momentum transfer for all alcohols. There are additional finer details across the ether alcohols for these activation barriers. These differences cancel out for the mathematical product of self-diffusion coefficient and viscosity (

Identifiers

PMID39139987
PMCPMC11317982

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.