ArticleNature communications2024
Elucidation of hemilabile-coordination-induced tunable regioselectivity in single-site Rh-catalyzed heterogeneous hydroformylation.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Heterogeneous hydroformylation of propene over surface rhodium coordinated by immobilized multi-N ligands.Science advances · 2026Article
- How single-atom catalysis transformed from a nanoscience curiosity into a new paradigm for heterogeneous catalysis.Nature nanotechnology · 2026Article
- Electronic and steric effects of phosphine ligands on the linear regioselectivity of propylene methoxycarbonylation.Communications chemistry · 2026Article
- Selective conversion of syngas to CNature communications · 2026Article
- Click Heterogenization of Phosphines Furnishes Recyclable Hydroformylation Catalysts that Reproduce Homogeneous Performance.Journal of the American Chemical Society · 2025Article
- Single-site ruthenium catalyst supported on zeolite for COScience advances · 2025Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Revealing key factors that modulate the regioselectivity in heterogeneous hydroformylation requires identifying and monitoring the dynamic evolution of the truly active center under real reaction conditions. However, unambiguous in situ characterizations are still lacking. Herein, we elaborately construct a series of Rh-POPs catalysts for propylene hydroformylation which exhibited tunable regioselectivity. Multi-technique approaches reveal the unique microenvironment of the diverse HRh(CO)(PPh
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