Access to 2-oxoazetidine-3-carboxylic acid derivatives via thermal microwave-assisted Wolff rearrangement of 3-diazotetramic acids in the presence of nucleophiles.

Ivan Lyutin, Vasilisa Krivovicheva, Grigory Kantin, Dmitry Dar'in

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Article in Beilstein journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 authors.

Ivan LyutinInstitute of Chemistry, Saint Petersburg State University, 26 Universitetskiy pr., Peterhof, Saint Petersburg 198504, Russian Federation.

Vasilisa KrivovichevaInstitute of Chemistry, Saint Petersburg State University, 26 Universitetskiy pr., Peterhof, Saint Petersburg 198504, Russian Federation.

Grigory KantinInstitute of Chemistry, Saint Petersburg State University, 26 Universitetskiy pr., Peterhof, Saint Petersburg 198504, Russian Federation.ORCID https://orcid.org/0000-0001-9141-680X

Dmitry Dar'inInstitute of Chemistry, Saint Petersburg State University, 26 Universitetskiy pr., Peterhof, Saint Petersburg 198504, Russian Federation.ORCID https://orcid.org/0000-0002-0413-7413

Funding

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6 · The paper itself

Abstract

In this work, we report an efficient approach to 2-oxoazetidine-3-carboxylic acid derivatives based on a thermally promoted Wolff rearrangement of diazotetramic acids in the presence of nucleophiles. The method allows easy variation of the substituent in the exocyclic acyl group by introducing different

Indexed as

diazotetramic acidsnucleophilesspirocyclesthermolysisWolff rearrangementβ-lactams

Identifiers

PMID39135658

DOI10.3762/bjoc.20.164

PMCPMC11318632

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