Evidence map›Paper›PMID 39134515›Full record

ArticleNature communications2024

Enantioselective S

Qifeng Lin, Yingdong Duan, Yao Li, Ruijun Jian, Kai Yang, Zongbin Jia, Yu Xia, Long Zhang, Sanzhong Luo

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Qifeng LinCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.
Yingdong DuanCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.ORCID http://orcid.org/0009-0001-0634-0810
Yao LiCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.
Ruijun JianMOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Department of Chemistry, Tsinghua University, Beijing, China.
Kai YangCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.
Zongbin JiaCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China.
Yu XiaMOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Department of Chemistry, Tsinghua University, Beijing, China.ORCID http://orcid.org/0000-0001-8694-9900
Long ZhangCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China. zhanglong@tsinghua.edu.cn.
Sanzhong LuoCenter of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, China. luosz@tsinghua.edu.cn.ORCID http://orcid.org/0000-0001-8714-4047

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22074075
6 · The paper itself

Abstract

Electrochemical reactions via carbocation intermediates remain fundamental transformations that build up molecular functionality and complexity in a sustainable manner. Enantioselective control of such processes is a great challenge in a highly ionic electrolyte solution. Here, we report an anodic generation of chiral α-imino carbocation intermediates by enamine catalysis. The chiral carbocation intermediates can be intercepted by a variety of nucleophiles such as alcohols, water and thiols with high stereoselectivity. The key S

Identifiers

PMID39134515
PMCPMC11319787

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.