Elastomeric Fire and Heat-Protective Materials Containing Functionally Active Microheterogeneous Systems.

Vladimir G Kochetkov, Daria A Kryukova, Daniil A Urzhumov, Oksana M Novopoltseva, Natalia A Keibal, Vladimir Burmistrov, Victor F Kablov

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Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

7 authors.

Vladimir G KochetkovDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Daria A KryukovaDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Daniil A UrzhumovDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Oksana M NovopoltsevaDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Natalia A KeibalDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Vladimir BurmistrovDepartment of Organic Chemistry, Volgograd State Technical University, 28 Lenina Avenue, Volgograd 400005, Russia.ORCID 0000-0002-8547-9166

Victor F KablovDepartment of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia.

Funding

Ministry of science and higher education of Russian Federation FZUS-2021-0013

6 · The paper itself

Abstract

This research aims to explore how functionally active structures affect the physical, mechanical, thermal, and fire-resistant properties of elastomeric compositions using ethylene-propylene-diene rubber as a base. The inclusion of aluminosilicate microspheres, microfibers, and a phosphorus-boron-nitrogen-organic modifier in these structures creates a synergistic effect, enhancing the material's heat-insulating properties by strengthening coke and carbonization processes. This results in a 12-19% increase in heating time for unheated sample surfaces and a 6-17% increase in residual coke compared to existing analogs. Microspheres help counteract the negative impact of microfibers on composition density and thermal conductivity, while the phosphorus-boron-containing modifier allows for controlling the formation of the coke layer.

Indexed as

aluminosilicate microfibersaluminosilicate microspheresfire-retardant propertiesheat resistancephosphorus–boron–nitrogen-containing modifierphysical–mechanical propertiessizing

Identifiers

PMID39125189

DOI10.3390/polym16152163

PMCPMC11314048

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