Evidence map›Paper›PMID 39124981›Full record

ArticleMolecules (Basel, Switzerland)2024

Transformation of Graphite Recovered from Batteries into Functionalized Graphene-Based Sorbents and Application to Gas Desulfurization.

Rodolfo Fernández-Martínez, Isabel Ortiz, M Belén Gómez-Mancebo, Lorena Alcaraz, Manuel Fernández, Félix A López, Isabel Rucandio, José María Sánchez-Hervás

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Rodolfo Fernández-MartínezChemistry Division, Technology Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.ORCID 0000-0002-8917-2372
Isabel OrtizSustainable Thermochemical Valorization Unit, Energy Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.ORCID 0000-0002-2230-0974
M Belén Gómez-ManceboChemistry Division, Technology Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.ORCID 0000-0002-1594-6275
Lorena AlcarazNational Centre for Metallurgical Research (CENIM), Spanish National Research Council (CSIC), Avda. Gregorio del Amo 8, 28040 Madrid, Spain.ORCID 0000-0003-4188-8993
Manuel FernándezChemistry Division, Technology Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.
Félix A LópezNational Centre for Metallurgical Research (CENIM), Spanish National Research Council (CSIC), Avda. Gregorio del Amo 8, 28040 Madrid, Spain.ORCID 0000-0001-9023-2996
Isabel RucandioChemistry Division, Technology Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.ORCID 0000-0003-2890-3976
José María Sánchez-HervásSustainable Thermochemical Valorization Unit, Energy Department, Research Centre for Energy, Environment and Technology (CIEMAT), 28040 Madrid, Spain.ORCID 0000-0002-8213-9123

Funding

Spanish Ministry of Science and Innovation, BIOENH2 project PLEC2023-010216Spanish Ministry of Science and Innovation, GONDOLA project PDC2021-120799-I00
6 · The paper itself

Abstract

The recycling and recovery of value-added secondary raw materials such as spent Zn/C batteries is crucial to reduce the environmental impact of wastes and to achieve cost-effective and sustainable processing technologies. The aim of this work is to fabricate reduced graphene oxide (rGO)-based sorbents with a desulfurization capability using recycled graphite from spent Zn/C batteries as raw material. Recycled graphite was obtained from a black mass recovered from the dismantling of spent batteries by a hydrometallurgical process. Graphene oxide (GO) obtained by the Tour's method was comparable to that obtained from pure graphite. rGO-based sorbents were prepared by doping obtained GO with NiO and ZnO precursors by a hydrothermal route with a final annealing step. Recycled graphite along with the obtained GO, intermediate (rGO-NiO-ZnO) and final composites (rGO-NiO-ZnO-400) were characterized by Wavelength Dispersive X-ray Fluorescence (WDXRF) and X-ray diffraction (XRD) that corroborated the removal of metal impurities from the starting material as well as the presence of NiO- and ZnO-doped reduced graphene oxide. The performance of the prepared composites was evaluated by sulfidation tests under different conditions. The results revealed that the proposed rGO-NiO-ZnO composite present a desulfurization capability similar to that of commercial sorbents which constitutes a competitive alternative to syngas cleaning.

Indexed as

desulfurizationreduced graphene oxiderGO-based compositessustainabilitysyngas cleaningZn/C battery waste

Identifiers

PMID39124981
PMCPMC11313908

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.