Photodetachment photoelectron spectroscopy shows isomer-specific proton-coupled electron transfer reactions in phenolic nitrate complexes.

Qinqin Yuan, Ziheng Zhang, Xiangtao Kong, Zicheng Ling, Hanhui Zhang, Longjiu Cheng, Xue-Bin Wang

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Article in Communications chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed

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2 citing papers in PubMed.

Ultrafast chemistry.Communications chemistry · 2026
Article
Role of Explicit Hydration in Scavenging of COInternational journal of molecular sciences · 2025
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7 authors.

Qinqin YuanDepartment of Chemistry, Anhui University, 230601, Hefei, China.

Ziheng ZhangDepartment of Chemistry, Anhui University, 230601, Hefei, China.

Xiangtao KongCollege of Chemistry and Chemical Engineering, Anyang Normal University, 455000, Anyang, China.ORCID http://orcid.org/0000-0003-3756-6481

Zicheng LingDepartment of Chemistry, Anhui University, 230601, Hefei, China.

Hanhui ZhangInstitute of Advanced Science Facilities, 518107, Shenzhen, China. zhanghh@mail.iasf.ac.cn.ORCID http://orcid.org/0000-0002-9011-3716

Longjiu ChengDepartment of Chemistry, Anhui University, 230601, Hefei, China. clj@ustc.edu.ORCID http://orcid.org/0000-0001-7086-6190

Xue-Bin WangPhysical Sciences Division, Pacific Northwest National Laboratory, Richland, WA, 99352, USA. xuebin.wang@pnnl.gov.ORCID http://orcid.org/0000-0001-8326-1780

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22273001

6 · The paper itself

Abstract

The oxidation of phenolic compounds is one of the most important reactions prevalent in various biological processes, often explicitly coupled with proton transfers (PTs). Quantitative descriptions and molecular-level understanding of these proton-coupled electron transfer (PCET) reactions have been challenging. This work reports a direct observation of PCET in photodetachment (PD) photoelectron spectroscopy (PES) of hydrogen-bonded phenolic (ArOH) nitrate (NO

Identifiers

PMID39122780

DOI10.1038/s42004-024-01257-5

PMCPMC11315994

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