Evidence map›Paper›PMID 39118599›Full record

ArticleChemical science2024

The forgotten borole: synthesis, properties and reactivity of a 1-boraindene.

Nele Wieprecht, Ivo Krummenacher, Leonie Wüst, Maximilian Michel, Sonja Fuchs, Samuel Nees, Marcel Härterich, Holger Braunschweig

Abstract read
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Nele WieprechtInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Ivo KrummenacherInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.ORCID https://orcid.org/0000-0001-9537-1506
Leonie WüstInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Maximilian MichelInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Sonja FuchsInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Samuel NeesInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Marcel HärterichInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.
Holger BraunschweigInstitute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany h.braunschweig@uni-wuerzburg.de.ORCID https://orcid.org/0000-0001-9264-1726

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The chemistry of unsaturated boron heterocycles, including five-membered boroles, continues to attract substantial interest. Herein, we report the synthesis of 1,2,3-triphenyl-1-boraindene, a benzene-fused borole, and examine its Lewis acidic, electrophilic, and antiaromatic properties relative to non-fused and bis-benzannulated boroles (9-borafluorenes). Reactivity studies with organic azides reveal that the boraindene behaves similarly to other boroles, undergoing ring expansion to a BN-naphthalene through insertion of a nitrogen atom.

Identifiers

PMID39118599
PMCPMC11304793

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.