ArticleNature protocols2024
Flux synthesis of two-dimensional covalent organic frameworks.
Article in Nature protocols, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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Who cites it
16 citing papers in PubMed.
- Ionic covalent organic frameworks with precisely engineered pyridinic nitrogen sites for light-driven gold recovery.Chemical science · 2026Article
- Fundamentals to Prospects: Synthetic Tuning of Covalent Organic Frameworks for Solid-State Hydrogen Storage.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Aqueous sonochemical synthesis of covalent organic frameworks.Nature protocols · 2026Review
- Wet Transfer of In Situ Grown Azo-Containing Two-Dimensional Conjugated Covalent Organic Framework Films for Photoswitchable Electronic Devices.Angewandte Chemie (International ed. in English) · 2026Article
- Conjugation-induced π-electron modulation in pyridazine-integrated covalent organic frameworks for SONature communications · 2026Article
- A Naphthalene-Based Three-Dimensional Covalent Organic Framework with acs Topology for Highly Selective Sulfur Hexafluoride Capture.Polymer science & technology (Washington, D.C.) · 2026Article
- The Reinforcing Effect of Cluster Materials in the Combustion of Hydrocarbon Fuels.International journal of molecular sciences · 2026Review
- Solvent-Free Synthesis of Covalent Organic Frameworks for High-Performance Room Temperature Ammonia Sensing.Micromachines · 2026Article
- Conjugation Lock-In Reinforced Sulfur-Heteropolycyclic Covalent Organic Frameworks with Asymmetric Electron Distribution for Photocatalytic Aerobic Oxidation Reactions.Journal of the American Chemical Society · 2026Article
- Covalent organic frameworks as infinite building units for metal-organic frameworks with compartmentalized pores.Nature chemistry · 2026Article
- Micro-Environment Programmable Quinoline COFs for High-Performance Photocatalytic HAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Homologous heteropolyaromatic covalent organic frameworks for enhancing photocatalytic hydrogen peroxide production and aerobic oxidation.Nature communications · 2025Article
- Umpolung of a covalent organic framework for high-performance cathodic sodium ion storage.Chemical science · 2025Article
- Surfactant-Assisted Construction of Covalent Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
- Recent Advances in the Utilization of Chiral Covalent Organic Frameworks for Asymmetric Photocatalysis.Molecules (Basel, Switzerland) · 2024Review
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Covalent organic frameworks (COFs) are crystalline porous polymers constructed from organic building blocks into ordered two- or three-dimensional networks through dynamic covalent bonds. Attributed to their high porosity, well-defined structure, tailored functionality and excellent chemical stability, COFs have been considered ideal sorbents for various separation applications. The synthesis of COFs mainly employs the solvothermal method, which usually requires organic solvents in sealed Pyrex tubes, resulting in unscalable powdery products and environmental pollution that seriously limits their practical applications. Herein, our protocol focuses on an emerging synthesis method for COFs based on organic flux synthesis without adding solvents. The generality of this synthesis protocol has been applied in preparing various types of COFs, including olefin-linked, imide-linked, Schiff-based COFs on both gram and kilogram scales. Furthermore, organic flux synthesis avoids the disadvantages of solvothermal synthesis and enhances the crystallization and porosity of COFs. Typically, COF synthesis takes 3-5 d to complete, and subsequent washing procedures leading to pure COFs need 1 d. The procedure for kilogram-scale production of COFs with commercially available monomers is also provided. The resulting COFs are suitable for separation applications, particularly as adsorbent materials for industrial gas separation and water treatment applications. The protocol is suited for users with prior expertise in the synthesis of inorganic materials and porous organic materials.
Indexed as
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39112651What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.