Evidence map›Paper›PMID 39095340›Full record

ArticleNature communications2024

Controlled interconversion of macrocyclic atropisomers via defined intermediates.

Xin Sun, Jin-Ku Bai, Yu-Dong Yang, Ke-Lin Zhu, Jia-Qi Liang, Xin-Yue Wang, Jun-Feng Xiang, Xiang Hao, Tong-Ling Liang, Ai-Jiao Guan and 2 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Xin SunCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.
Jin-Ku BaiCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.
Yu-Dong YangCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.ORCID http://orcid.org/0000-0001-6891-7470
Ke-Lin ZhuCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.
Jia-Qi LiangCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.ORCID http://orcid.org/0000-0003-2704-6984
Xin-Yue WangCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China.
Jun-Feng XiangInstitute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.ORCID http://orcid.org/0000-0002-2101-1409
Xiang HaoInstitute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Tong-Ling LiangInstitute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Ai-Jiao GuanInstitute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Ning-Ning WuInstitute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Han-Yuan GongCollege of Chemistry, Beijing Normal University, Beijing, 100875, PR China. hanyuangong@bnu.edu.cn.ORCID http://orcid.org/0000-0003-4168-7657

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21971022National Natural Science Foundation of China (National Science Foundation of China) 92156009
6 · The paper itself

Abstract

Macrocyclic conformations play a crucial role in regulating their properties. Our understanding of the determinants to control macrocyclic conformation interconversion is still in its infancy. Here we present a macrocycle, octamethyl cyclo[4](1,3-(4,6)-dimethylbenzene)[4]((4,6-benzene)(1,3-dicarboxylate) (OC-4), that can exist at 298 K as two stable atropisomers with C

Identifiers

PMID39095340
PMCPMC11297318

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.