Evidence map›Paper›PMID 39092131›Full record

ArticleChemical science2024

Real-time observation of sub-100-fs charge and energy transfer processes in DNA dinucleotides.

Vasilis Petropoulos, Lara Martinez-Fernandez, Lorenzo Uboldi, Margherita Maiuri, Giulio Cerullo, Evangelos Balanikas, Dimitra Markovitsi

Abstract read
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Vasilis PetropoulosDipartimento di Fisica, Politecnico di Milano Piazza Leonardo da Vinci 32 I-20133 Milano Italy giulio.cerullo@polimi.it.ORCID https://orcid.org/0009-0004-8300-6594
Lara Martinez-FernandezInstituto de Química Física Blas Cabrera, Consejo Superior de Investigaciones Científicas Calle Serrano 119 Madrid 28006 Spain lmartinez@iqf.csic.es.
Lorenzo UboldiDipartimento di Fisica, Politecnico di Milano Piazza Leonardo da Vinci 32 I-20133 Milano Italy giulio.cerullo@polimi.it.ORCID https://orcid.org/0000-0002-6969-4894
Margherita MaiuriDipartimento di Fisica, Politecnico di Milano Piazza Leonardo da Vinci 32 I-20133 Milano Italy giulio.cerullo@polimi.it.ORCID https://orcid.org/0000-0001-9351-8551
Giulio CerulloDipartimento di Fisica, Politecnico di Milano Piazza Leonardo da Vinci 32 I-20133 Milano Italy giulio.cerullo@polimi.it.ORCID https://orcid.org/0000-0002-9534-2702
Evangelos BalanikasDepartment of Physical Chemistry, University of Geneva CH-1211 Geneva-4 Switzerland.ORCID https://orcid.org/0000-0002-2811-1525
Dimitra MarkovitsiUniversité Paris-Saclay, CNRS, Institut de Chimie Physique, UMR8000 91405 Orsay France dimitra.markovitsi@universite-paris-saclay.fr.ORCID https://orcid.org/0000-0002-2726-305X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Using as showcase the DNA dinucleotide 5'-dTpdG-3', in which the thymine (T) is located at the 5' end with respect to the guanine (G), we study the photoinduced electronic relaxation of coupled chromophores in solution with an unprecedented refinement. On the one hand, transient absorption spectra are recorded from 20 fs to 45 ps over the 330-650 nm range with a temporal resolution of 30 fs; on the other hand, quantum chemistry calculations determine the ground state geometry of the 4 possible conformers with stacked nucleobases, the associated Franck-Condon states, and map the relaxation pathways leading to excited state minima. Important spectral changes occurring before 100 fs are correlated with concomitant G

Identifiers

PMID39092131
PMCPMC11290326

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.