ArticleChemical science2024
Tracking the conical intersection dynamics for the photoinduced Jahn-Teller switch of a Mn(iii) complex.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Excitation energy dependence of ultrafast Jahn-Teller switching in Mn(III) acetylacetonate.Physical chemistry chemical physics : PCCP · 2026Article
- Jahn-Teller distortion controls electron transfer in photoexcited Cu(i) donor-acceptor systems.Chemical science · 2026Article
- Multiscale phase nucleation driven by photoinduced polarons in a volume-changing material.Nature materials · 2026Article
- Capturing Ultrafast Spin Dynamics in Single-Molecule Magnets Using Femtosecond X-ray Emission Spectroscopy.The journal of physical chemistry letters · 2025Article
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Authors and funding
4 authors.
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Abstract
Octahedral Mn(iii) ions predominantly exhibit an axially elongated Jahn-Teller (JT) distortion, which is responsible for their large uniaxial magnetic anisotropy. As a result, they are often used in the synthesis of single-molecule magnets (SMMs). Modulation of the JT distortion using femtosecond laser pulses could offer a route to controlling the magnetisation direction, and therefore is promising for the development of data storage devices that work on ultrafast timescales. Photoinduced switching of the distortion from an axially elongated to an axially compressed structure has been demonstrated for various Mn(iii) complexes. However, the dynamics around the region of the conical intersection for the photoinduced JT switch remains unclear. Here, ultrafast transient absorption spectra were recorded for solutions of tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(iii) (Mn(dpm)
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