ArticleACS sustainable chemistry & engineering2024
Pilot Scale Electrolysis of Peroxodicarbonate as an Oxidizer for Lignin Valorization.
Article in ACS sustainable chemistry & engineering, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The trial behind it
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Who cites it
2 citing papers in PubMed.
- Nickel Foam Electrodes-A Versatile, Powerful, and Readily Available Tool in Electro-Organic Synthesis.Chemical record (New York, N.Y.) · 2026Review
- Highly Concentrated Peroxodicarbonate for Efficient Oxidative Degradation of Kraft Lignin.ChemSusChem · 2025Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A pilot scale plant at Technology Readiness Level (TRL) 6 comprising an electrochemical ex-cell continuous production of sodium peroxodicarbonate and a thermal depolymerization plug flow reactor for kraft lignin conversion is established. Due to the labile nature of the "green" oxidizer peroxodicarbonate, special attention must be paid to the production parameters in order to optimize its use. A simplified design model describing steady-state and transient operations is formulated and finally validated against experimental data from the electrolysis setup. Design trade-offs are visualized, and their impact on specific energy consumption is evaluated. The pilot plant was operated for a 20-month period for more than 1200 h on-stream. Optimized process conditions result in vanillin yields of 8 wt % and thus prove the successful scale-up.
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Registered trials
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