ArticleJournal of the American Chemical Society2024
Enhanced Electrochemiluminescence at the Gas/Liquid Interface of Bubbles Propelled into Solution.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
16 citing papers in PubMed.
- Mechanistic insights into electrochemiluminescence: fueling advances in bioanalysis and imaging.Chemical science · 2026Review
- Rubrene-Oxalate Electrochemiluminescence Reveals Physicochemical Properties of Triphasic Boundaries.Chemical & biomedical imaging · 2026Article
- Electrochemiluminescence Imaging for In Situ Electrocatalysis Characterization: Recent Progress and Mechanistic Insights.Chemical & biomedical imaging · 2026Review
- Operando Optical Imaging Reveals Beyond-Meniscus Nanoelectrochemistry Mediated by a Nanometric Wetting Film.Chemical & biomedical imaging · 2026Article
- Localized Accumulation of Tri-n-Propylamine Prolongs Electrochemiluminescence for Tumor Model Spheroid Analysis.Angewandte Chemie (International ed. in English) · 2026Article
- Axial Coordination Orchestrates Antibonding-State Fermi-Level Proximity and Oxygen Affinity in Single-Atom Iron for Selective Chemiluminescence.Angewandte Chemie (International ed. in English) · 2026Article
- Illuminating the Interface: In Situ Optical Insights Into Two-Electron ORR Pathways for HAdvanced materials (Deerfield Beach, Fla.) · 2026Review
- Reactivity at Bubble Interfaces.Micromachines · 2026Article
- Redox-mediator enhanced electrochemiluminescence under non-aqueous conditions.Chemical science · 2026Article
- Rationalized Volcano Plot in Heterogeneous Electrochemiluminescence.ACS electrochemistry · 2026Article
- From Microscale to Nanoscale Shadow Electrochemiluminescence Microscopy.Angewandte Chemie (International ed. in English) · 2026Article
- Radical Electroprecipitation Prolongs "Electro"chemiluminescence of the Tris(2,2'-bipyridyl)ruthenium(II) and Tri-Journal of the American Chemical Society · 2026Article
- Magnetoelectrochemical Rotation of Light Emitting Graphene Monolayers.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Multiphase Electrochemiluminescence of Microdroplets and Radical Salts.Accounts of chemical research · 2025Article
- Real-Time Visualization of an Elusive, Strong Reducing Agent during Tris(2,2'-bipyridyl)ruthenium(II) Electro-Oxidation in Water.Journal of the American Chemical Society · 2025Article
- Real-Time Visualization of Endogenous HChemical & biomedical imaging · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electrochemiluminescence (ECL) is typically confined to a micrometric region from the electrode surface. This study demonstrates that ECL emission can extend up to several millimeters away from the electrode employing electrogenerated chlorine bubbles. The mechanism behind this bubble-enhanced ECL was investigated using an Au microelectrode in chloride-containing and chloride-free electrolyte solutions. We discovered that ECL emission at the gas/solution interface is driven by two parallel effects. First, the bubble corona effect facilitates the generation of hydroxyl radicals capable of oxidizing luminol while the bubble is attached to the surface. Second, hypochlorite generated from chlorine sustains luminol emission for over 200 s and extends the emission range up to 5 mm into the solution, following bubble detachment. The new approach can increase the emission intensity of luminol-based assays 5-fold compared to the conventional method. This is demonstrated through a glucose bioassay, using a midrange mobile phone camera for detection. These findings significantly expand the potential applications of ECL by extending its effective range in time and space.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.