Evidence map›Paper›PMID 39087465›Full record

ArticleAngewandte Chemie (International ed. in English)2024

Resonance-Assisted Self-Doping in Robust Open-Shell Ladder-Type Oligoaniline Analogues.

Mingwan Leng, Turki M Alturaifi, Josiah Pearce, Hengyu Lin, Guanghua Yu, Mohammed Al-Hashimi, Hong-Cai Zhou, Peng Liu, Lei Fang

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Mingwan LengDepartment of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843-3255, USA.ORCID https://orcid.org/0000-0001-5033-9967
Turki M AlturaifiDepartment of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, PA 15260, USA.ORCID https://orcid.org/0000-0002-6379-1669
Josiah PearceDepartment of Materials Science and Engineering, Texas A&M University, 3003 TAMU, College Station, TX 77843-3003, USA.
Hengyu LinDepartment of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843-3255, USA.ORCID https://orcid.org/0000-0002-0332-3409
Guanghua YuDepartment of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843-3255, USA.
Mohammed Al-HashimiCollege of Science and Engineering, Hamad Bin Khalifa University P. O. Box 34110, Doha, Qatar.ORCID https://orcid.org/0000-0001-6015-2178
Hong-Cai ZhouDepartment of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843-3255, USA.ORCID https://orcid.org/0000-0002-9029-3788
Peng LiuDepartment of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, PA 15260, USA.ORCID https://orcid.org/0000-0002-8188-632X
Lei FangDepartment of Chemistry, Texas A&M University, 3255 TAMU, College Station, TX 77843-3255, USA.ORCID https://orcid.org/0000-0003-4757-5664

Funding

Computational Models for Reactivity and Selectivity in Transition Metal-Catalyzed Olefin FunctionalizationR35GM128779 · NIGMS · UNIVERSITY OF PITTSBURGH AT PITTSBURGH · PI Peng Liu · 2018 to 2026
$2.9M
National Science Foundation OAC-2117681, OAC-1928147 and OAC-1928224NIGMS NIH HHS R35 GM128779Qatar National Research Fund ARG01-0522-230270Welch Foundation A-0030Welch Foundation A-1898
6 · The paper itself

Abstract

A novel resonance-assisted self-doping mechanism has been demonstrated in ladder-type oligoaniline-derived organic conductors. The new class of compounds has a unique structure incorporating acidic phenolic hydroxyl groups into the ladder-type cyclohexadiene-1,4-diimine core, enabling efficient resonance-assisted proton transfer and electronic doping without the need for external dopants. Mechanistic and computational studies confirm the open-shell, zwitterionic nature of the self-doped state and the significant role played by the dielectric environment. This new self-doping mechanism allows for higher stability and durability in the material's electronic performance. The self-doped form retains durability under harsh conditions and maintains its properties over extended periods of time.

Indexed as

dopingfused ring π-systemoligoanilineopen-shellorganic conductorproton transfer

Identifiers

PMID39087465
PMCPMC11812591

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.