ArticleRSC advances2024
Deciphering the doublet luminescence mechanism in neutral organic radicals: spin-exchange coupling, reversed-quartet mechanism, excited-state dynamics.
Article in RSC advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- NAST 2.0: Magnetic Field Effects and Marcus-Levich-Jortner Theory for Complex Open-Shell Systems.ACS omega · 2026Article
- A Qualitative Approach for Predicting Enhanced Intersystem Crossing in Chromophore-Radical Systems.The journal of physical chemistry letters · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
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Authors and funding
3 authors.
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Abstract
Neutral organic radical molecules have recently attracted considerable attention as promising luminescent and quantum-information materials. However, the presence of a radical often shortens their excited-state lifetime and results in fluorescence quenching due to enhanced intersystem crossing (EISC). Recently, an experimental report introduced an efficient luminescent radical molecule, tris(2,4,6-trichlorophenyl)methyl-carbazole-anthracene (TTM-1Cz-An). In this study, we systematically performed quantum theoretical calculations combined with the path integral approach to quantitatively calculate the excited-state dynamics processes and spectral characteristics. Our theoretical findings suggest that the sing-doublet D
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